CERIUM


Atomic Number: 58

Atomic Symbol: Ce

Atomic Weight: 140.12

Electron Configuration: -19-9-2


(named for the asteroid Ceres, which was discovered in 1801 only 2 years before the element) Discovered in 1803 by Klaproth and by Berzelius and Hisinger; metal prepared by Hillebrand and Norton in 1875. Cerium is the most abundant of the metals of the so-called rare-earths. It is found in a number of minerals including allanite (also known as orthite), monazite, bastnasite, certie, and samarskite. Monazite and bastnasite are presently the two more important sources of cerium. Large deposits of monazite found on the beaches of Travancore, India, in river sands in Brazil, and deposits of allanite in the western United States, and bastnasite in Southern California will supply cerium, thorium, and the other rare-earth metals for many years to come. Metallic cerium is prepared by metallothermic reduction techniques, such as by reducing cerous fluoride with calcium, or by electrolysis of molten cerous chloride or others. The metallothermic technique is used to produce high-purity cerium. Cerium is especially interesting because of its variable electronic structure. The energy of the inner 4f level is nearly the same as that of the outer or valence electrons, and only small amounts of energy are required to change the relative occupancy of these electronic levels. This gives rise to dual valency states. For example, a volume change of about 10% occurs when cerium is subjected to high pressures or low temperatures. It appears that the valence changes from about 3 to 4 when it is cooled or compressed. The low temperature behavior of cerium is complex. Cerium is an iron-gray lustrous metal. It is malleable, and oxidizes very readily at room temperature, especially in moist air. Except for europium, cerium is the most reactive of the "rare-earth" metals. It slowly decomposes in cold water and rapidly in hot water. Alkali solutions and dilute and concentrated acids attack the metal rapidly. The pure metal is likely to ignite if scratched with a knife. Ceric slats are orange red or yellowish; cerous salts are usually white. Cerium is a coponent of misch metal, which is extensively used in the manufacture of pyrophoric alloys for cigarette lighters, etc. While cerium is not radioactive, the impure commercial grade may contain traces of thorium, which is radioactive. The oxide is an important constituent of incandescent gas mantles and is emerging as a hydrocarbon catalyst in "self cleaning" ovens. In this application it can be incorporated into oven walls to prevent the collection of cooking residues. As ceric sulfate it finds extensive use as a volumetric oxidizing agent in quantitative analysis. Cerium compounds are used in the manufacture of glass, both as a component and as a decolorizer. The oxide if finding increased use as a glass polishing agent instead of rouge, for it is much faster than rouge in polishing glass surfaces. Cerium, with other rare earths, is used in carbon-arc lighting, especially in the motion picture industry. It is also finding use as an important catalyst in petroleum refining and in metallurgical and nuclear applications. In small lots, 99.9% cerium costs about $125/kg.